Photogenerated free carrier dynamics in metal and semiconductor single-walled carbon nanotube films.

نویسندگان

  • Matthew C Beard
  • Jeffrey L Blackburn
  • Michael J Heben
چکیده

Time-resolved THz spectroscopy (TRTS) is employed to study the photogenerated charge-carrier dynamics in transparent films of single-walled carbon nanotubes (SWNTs). Two films were investigated: a film with 94% semiconducting-type tubes (s-SWNTs) and a film with only 7% s-SWNT and 93% metal-type tubes (m-SWNTs). We conclude that charge-carriers are generated with >60% yields at low light intensities in both films. Free-carriers are generated by a linear exciton dissociation process that occurs within -1 ps and is independent of excitation wavelength or tube type.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Fabrication of Photodetectors using Transparent Carbon Nanotube Films

Carbon nanotubes are promising nanoscale materials for novel electrical, mechanical, chemical, and biological device and sensors based on its outstanding properties. Single walled carbon nanotubes can be either semiconducting or metallic material depending on its structures. However, controlling the structure is quite challenging with current technologies. For the network formation of the singl...

متن کامل

Increasing the hydrogen storage capacity of single-walled carbon nanotube (SWNT) through facile impregnation by TiO2, ZrO2 and ZnO nanocatalysts

Various nanocomposites of TiO2, ZnO and ZrO2 decorated single wall Carbon nanotubes (SWNTs) were fabricated by facile and template free continuous ultrasonication/stirring of virgin metal oxide nanopowders and SWNTs in ethanol under UV-light illumination. The TEM micrographs showed that nanoparticles (NPs) were uniformly dispersed and bonded on the surface of SWNTs. The results of XRD as well a...

متن کامل

Carbon Nanotube “T Junctions”: Nanoscale Metal-Semiconductor-Metal Contact Devices

Stable “T junctions” of single-walled carbon nanotubes forming one of the smallest prototypes of microscopic metal-semiconductor-metal contacts are proposed. The structures have been found to be local minima of the total energy on relaxation with a generalized tight-binding molecular dynamics scheme. These quasi-2D junctions could be the building blocks of nanoscale tunnel junctions in a 2D net...

متن کامل

Interaction of some heavy metal ions with single walled carbon nanotube

The interaction between some heavy metal ions such as of Pb(II), Cd(II) and Cu(II) ions from aqueous solution adsorbed by single walled carbon nanotube (SWCNTs) and carboxylate group functionalized single walled carbon nanotube (SWCNT-COOH) surfaces were studied by atomic absorption spectroscopy. The effect of contact time, pH, initial concentration of ion, ionic strength and temperature on the...

متن کامل

Interaction of some heavy metal ions with single walled carbon nanotube

The interaction between some heavy metal ions such as of Pb(II), Cd(II) and Cu(II) ions from aqueous solution adsorbed by single walled carbon nanotube (SWCNTs) and carboxylate group functionalized single walled carbon nanotube (SWCNT-COOH) surfaces were studied by atomic absorption spectroscopy. The effect of contact time, pH, initial concentration of ion, ionic strength and temperature on the...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Nano letters

دوره 8 12  شماره 

صفحات  -

تاریخ انتشار 2008